most weapons were made of bronze or copper up until 100 BCE whenthey started to make weapons out of iron.
The ancient primary Greek weapons like The Dory was made up ofeither iron or bronze. The Spartan swords were made up of ironblade, the Kopis were also made up of iron and the shields weremade out of wood with an outer layer of bronze.
Ancient greek weapons were made of copper or bronze. Bronze is an alloy of copper and tin. The very first weapon in Greece was copper then bronze. Later (c.1000BC) iron weapons came into use. Iron tools also allowed the Greeks to make sophisticated armour and shields from bronze.

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